Product ID:3254, PRIMEEZ ACRYLIC PRIMER SURFACER, GRAY
MSDS Date:03/06/1999
FSC:8010
NIIN:00N092993
Status Code:A
MSDS Number: CJWHV

MARTIN SENOUR PAINTS

101 PROSPECT AVENUE
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

22.00.

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL see Table Z-2

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

33.00.

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 980 MG/M3;400 PPM

ACGIH TLV: 983 MG/M3;400 PPM

16.00.

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

12.50.

CAS: 110-19-0

RTECS: AI4025000

OSHA PEL 700 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TALC

CAS: 14807-96-6

RTECS: WW2710000

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 2 MG/M3

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

0.00.

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TO MINIMIZE EXPOSURE, FOLLOW
RECOMMENDATIONS FOR PROPER USE, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT. EFFECTS OF OVEREXPOSURE: IRRITATION OF EYES,
SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOU S SYSTEM DEPRESSION.
EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY
DEATH. CHRONIC: TOLUENE APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS LIST. SEEK CONSULTATION FROM APPROPRIATE
HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND
SAFE HANDLING AND EXPOSURE INFORMATION .
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOLUME
65, PAGE 149, 1998: GROUP 2B. ANIMAL: LUNG.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE
EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE REUSE. E YES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST
15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL
ATTENTION.

Flash Point Method:PMCC
Flash Point:=4.4C, 40.F
Lower Limits:1.0%
Upper Limits:12.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE
INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED TO COOL CLO SED CONTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:FLAMM CLASSIFICATION: RED LABEL--FLAMM,
FLASH POINT <100F. KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT,
ELEC EQUIP, SPKS, & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATIO N TO HOT SURFS REQUIRES SPECIAL
PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH
HAZ. (OTHER INFO)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:DOL STOR CATEGORY: 1B. CONTENTS ARE
FLAMM. KEEP AWAY FROM HEAT, SPKS, & OPEN FLAME. DURING USE & UNTIL
ALL VAPS ARE GONE: KEEP AREA VENTILATED; DO NOT SMOKE; EXTING ALL
FLAMES, PILOT LIGHTS, & HEATERS ; TURN OFF STOVES, ELEC TOOLS &
APPLIANCES, & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE.
Other Precautions:USE APPRVD BONDING & GROUNDING PROC. KEEP CONTR
CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CONTRS W/COMPLETE &
APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF
CHILDREN. USE ONLY W/A DEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CONT W/SKIN & EYES. (SUP DAT)

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LMITS BY VENT, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS IN INGREDIENTS SE CTION. WHEN SANDING/ABRADING
DRIED FILM, WEAR DUST/MIST RESPIRATOR APPROVED BY NIOSH FOR DUST
WHICH MAY BE GENERATED FROM PRODUCT, UNDERLYING PAINT/ABRASIVE.
Ventilation:LOC EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOS
IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. REFER TO OSHA
STANDARDS 1910.94, 1910.107, 1910.108.
Protective Gloves:GLOVES RECOMMENDED BY GLOVE SUPPLIER. WEAR IMPERVIOUS
GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
OTHER PREC: THIS COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE
PARTICULATES (LISTED "AS DUST" IN INGS SECTION) WHICH MAY BE
PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM.
INTENTI ONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN
BE HARMFUL/FATAL.

Boiling Pt:>81.1C, 178.F
B.P. Text:178F - 246F
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Spec Gravity:1.21
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:63

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR
IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE
NUMBERS. INCINERATE IN APPROVED FACILIT Y. DO NOT INCINERATE CLOSED
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGUL ATIONS REGARDING POLLUTION.

Toxicological Information:CHRONIC HEALTH HAZARDS: CARBON BLACK IS
CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B)
BASED ON EXPERIMENTAL ANIMAL DATA; HOWEVER, THERE IS INSUFFICIENT
EVIDENCE IN HUMANS FOR ITS CA RCINOGENICITY. PROLONGED OVEREXPOSURE
TO SOLVENT INGREDIENTS IN INGREDIENTS SECTION MAY CAUSE ADVERSE
EFFECTS TO THE LIVER, URINARY, CARDIOVASCULAR AND REPRODUCTIVE
SYSTEMS. RATS EXPOSED TO TITANIUM D IOXIDE DUST AT 250 MG/M3
DEVELOPED LUNG CANCER; HOWEVER, SUCH EXPOSURE LEVELS ARE NOT
ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANEN T BRAIN AND
NERVOUS SYSTEM DAMAGE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.

Transport Information:BILL OF LADING DESCRIPTION: NO DATA AVAILABLE.

SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: TOLUENE, CAS # 108-88-3, 31% BY WEIGHT; METHYL
ISOBUTYL KETONE, CAS # 108-10-1, 6% BY WEIGHT.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.